Metallosupramolecular assemblies

Scheme 6.14 Synthesis of nanoboxes 50 and 51 using metallosupramolecular assembly [59], Reagents and conditions (a) [Cu(MeCN)4]PF6, CH2CI2, rt (b) AgPF6, CH2CI2, rt.

Constable, E.C. and Cargill Thompson, A.M.W. (1992) Ligand reactivity in iron(II) complexes of 4 -(4 "-pyridyl)-2,2 6, 2"-terpyridine J. Chem. Soc., Dalton Trans., 2947-2950 Constable, E.C. and Cargill Thompson, A.M.W. (1994) Pendant-functionalised ligands for metallosupramolecular assemblies ruthenium(II) and osmium(II) complexes of 4 -(4-pyridyl)-2,2 6, 2"-terpyridine J. Chem. Soc., Dalton Trans., In the press... 

Yoshimoto S, Nishiyama K (2013) One-pot formation of a metallosupramolecularly assembled and redox-active adlayer at the solid-liquid interface. J Inorg Organomet Polym Mater 23 233-238. doi 10.1007/sl0904-012-9743-3... 

Yoshioka R (2007) Racemization, Optical Resolution and Crystallization-Induced Asymmetric Transformation of Amino Acids and Pharmaceutical Intermediates. 269 83-132 You C-C, Dobrawa R, Saha-Moller CR, Wiirthner F (2005) Metallosupramolecular Dye Assemblies. 258 39-82 Yu J, see Dittrich M (2007) 268 319-347... 

You C-C, Dobrawa R, Saha-Moller CR, Wiirthner F (2005) Metallosupramolecular Dye Assemblies. 258 39-82... 

Schroder T, BrodbeckR, Letzel M, Mix A, Schnatwinkel B, Tonigold M, Volkmer D, Mattay J (2008) A self-assembling metallosupramolecular cage based on cavitand-terpyridine subunits. Tetrahedron Lett 49 5939... 

Fig. 5 Generation of multifunctionality/multivalency by self-assembly. Octa-valency from either hydrazide and dialdehyde components/subunits (left), or preformed ligands (top right) in the case of the formation of [2x2] grid-type metallosupramolecular architectures. Insert. Schematic representation of the generation of hexadeca-valency from tetrasubstituted ligand molecules...

Cao XY et al (2007) Generation of [2X2] grid metallosupramolecular architectures from preformed ditopic bis(acylhydrazone) ligands and through component self-assembly. Eur J Inorg Chem 2944—2965. 

The measurements visualize the impact of metal-ligand interactions and a metallosupramolecular self-assembly process in two dimensions, where the... 

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