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Metalloporphyrins ligand interactions

A pictorial representation of the various kinds of cis and tram interactions in metalloporphyrins is shown in Fig. 1 this kind of illustration has been used by Phillips and Williams in their textbook chapter on cis and tram effects (2). The transmission paths A-F will be used to explain the mutual electronic interactions of the porphyrin and the axial ligands in Chapters 5 to 9. The general situation is elaborated in Chapters 3 and 4. [Pg.85]

Tsuda and Kasai studied the interaction of 02 (203) with metalloporphyrins and the effect of imidazole on it (204) and concluded that in the 02 adducts, an imidazole ligand induces a strong electron donation to 02, resulting in the weak 0-0 bond. [Pg.291]

See other pages where Metalloporphyrins ligand interactions is mentioned: [Pg.3]    [Pg.167]    [Pg.167]    [Pg.170]    [Pg.204]    [Pg.3]    [Pg.167]    [Pg.167]    [Pg.170]    [Pg.204]    [Pg.236]    [Pg.1008]    [Pg.296]    [Pg.1008]    [Pg.4462]    [Pg.172]    [Pg.251]    [Pg.291]    [Pg.99]    [Pg.70]    [Pg.275]    [Pg.280]    [Pg.217]    [Pg.225]    [Pg.212]    [Pg.73]    [Pg.98]    [Pg.110]    [Pg.193]    [Pg.89]    [Pg.364]    [Pg.439]    [Pg.59]    [Pg.273]    [Pg.280]    [Pg.307]    [Pg.72]    [Pg.189]    [Pg.1230]    [Pg.34]    [Pg.180]    [Pg.68]    [Pg.279]    [Pg.308]    [Pg.74]    [Pg.2112]    [Pg.2158]    [Pg.5526]    [Pg.5527]    [Pg.205]    [Pg.57]    [Pg.7]    [Pg.10]    [Pg.19]   
See also in sourсe #XX -- [ Pg.167 , Pg.170 ]



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