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Metallic lanthanides ionization energy

Gas Phase Photoelectron Spectra of d- and /-Block Organometallic Compounds Table 10. Ionization energies (eV) of lanthanide and actinide cyclopentadienyl metal halides... [Pg.77]

Tin(IV) oxide is more basic in water than carbon dioxide because tin has more metallic character than carbon. 14.38(a) Ionization energy generally decreases down a group, (b) The deviations (increases) from the expected trend are due to the presence of the first transition series between Si and Ge and of the lanthanides between Sn and Pb. (c) Group 3A(13) 14.41 Atomic size in-... [Pg.818]

Fig. 9.6. Melting slope dT/dP and ionization energy I for divalent lanthanide ions against atomic number, from Jayaraman (1965) and Johansson and Rosengren (1975> respectively. To be noted is the remarkable resemblance of the two sets of data. The smooth curve is the interpolated binding energy difference between divalent and trivalent metallic states. Fig. 9.6. Melting slope dT/dP and ionization energy I for divalent lanthanide ions against atomic number, from Jayaraman (1965) and Johansson and Rosengren (1975> respectively. To be noted is the remarkable resemblance of the two sets of data. The smooth curve is the interpolated binding energy difference between divalent and trivalent metallic states.
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