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Weak single bonds metal hydrides

Some important hydride complexes are available by a reaction that appears to be the hydrogenolysis of a metal-metal single bond (Equation 3.103). However, this reaction occurs only when the metal-metal bond is weak, and probably proceeds via the third-order reaction with of the two metalloradicals [i.e., CofCO) ] formed when the metal-metal bond dissociates. - More recent observations of the reaction of monomeric metalloradicals with Hj are shown in Equations 3.104 and 3.105. - ... [Pg.125]


See other pages where Weak single bonds metal hydrides is mentioned: [Pg.75]    [Pg.86]    [Pg.85]    [Pg.133]    [Pg.269]    [Pg.442]    [Pg.1080]    [Pg.325]    [Pg.134]    [Pg.27]    [Pg.27]    [Pg.28]   
See also in sourсe #XX -- [ Pg.225 ]




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