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Metal hydrides diselenides

Various reducing agents have been used for the generation of selenolates from diselenides or selenocyanates. Alkali metals M (M = Li, Na, K)149,150 or alkali hydrides MH (M = Li, Na, K)151,152 can generate the corresponding selenolate anions such as 80 these are more reactive than the borane complexes of type 77 (Scheme 15). Diaryl diselenides are easier reduced than dialkyl diselenides, but the mechanism for the reduction of selenocyanates is complex and can lead to either diselenides or selenolates.153,154... [Pg.468]


See other pages where Metal hydrides diselenides is mentioned: [Pg.4317]    [Pg.57]    [Pg.59]    [Pg.405]    [Pg.561]    [Pg.4316]    [Pg.57]    [Pg.59]    [Pg.41]   
See also in sourсe #XX -- [ Pg.219 ]




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