Metal hydrazine carboxylate N2H3COO

Metal hydrazine carboxylates [M(N2H3COO)2-(N2H4)2] are prepared from aqueous solutions of metals salts with hydrazine carboxylic acid in hydrazine hydrate ... [Pg.17]

Metal hydrazine carboxylates are formed by reaction of the respective metal ions with a saturated solution of ammonium carbonate in hydrazine hydrate [5]. The products precipitate instantaneously. The formation of metal hydrazine carboxylates by the reaction of metal ions with the ligand N2H3COO (1.23) can be represented by the following general equation ... [Pg.134]

METAL HYDRAZINE CARBOXYLATE HYDRAZINES - M(N2H3COO)2 (N2H4)2... [Pg.152]

SOLID SOLUTIONS OF HYDRAZINIUM METAL HYDRAZINE CARBOXYLATE HYDRATES - N2H5 Mv (Co/Ee/Mn)22 (N2H3COO)3 H2O... [Pg.160]

Quite recently, a soUd solution of hydrazinium mixed metal hydrazine carboxylate complex of the type (N2H5)Nio.5Coo.5(N2H3COO)3-H20 has been prepared by mixing the respective metal solutions in a molar ratio of 1 1 [4]. To this solution hydrazine carboxylic acid is added until... [Pg.166]

Analogous to the synthesis method adopted for the preparation of hydrazinium metal sulfite hydrates, hydrazinium lanthanide sulfite hydrates, N2H5Ln(S03)2(H20)2, can be synthesized by the addition of hydrazine sulfite monohydrate to the respective anhydrous lanthanide hydrazine carboxylates M(N2H3COO)2 [10]. [Pg.215]

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