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Metal clusters halogen bridges

Fig. 5.9 The inter-cluster halogen (i.e., iodine) bridging between the octahedral metal clusters in the structures of both Na[(Zr6B)Cl3.9ho.i] and Cs[(Zr6B)Cl2.2hi.8... Fig. 5.9 The inter-cluster halogen (i.e., iodine) bridging between the octahedral metal clusters in the structures of both Na[(Zr6B)Cl3.9ho.i] and Cs[(Zr6B)Cl2.2hi.8...
The best-known examples of noncarbonyl clusters containing three metal atoms are the rhenium trihalides [(ReO,)iJ and their derivatives. The basic structural unit is shown in Fig. 16.62a. Each rhenium atom is bunded to the other two rhenium atoms directly by metal-metal bonds and indirectly by a bridging halogen ligand. In addition. [Pg.942]

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See also in sourсe #XX -- [ Pg.2 , Pg.685 ]



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