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Mercury chains

Formation of the Group-IB or -IIB-Group-IB or -MB Metal Bonds 8.2.5. Mercury Chain Compounds... [Pg.525]

Inner-Transition Metal to Transition and Inner-Transition Metal Bond 105 9.2.12. Inner Transition Metal Complexes With Chains of Metal Atoms 9.2.12.3. Compounds Containing Mercury Chains... [Pg.215]

Figure 1. A biased comparison between transition and posttransition element clusters. The figure shows the cluster frameworks and surrounding atoms at bonding distances in (A) the carbon-centered carbonyl cluster Rh6C(CO)i5, (C) S 9(AsF6)2, and (B) the infinite and crystallo-graphically incommensurate mercury chains in Hg3, s(AsF6). Figure 1. A biased comparison between transition and posttransition element clusters. The figure shows the cluster frameworks and surrounding atoms at bonding distances in (A) the carbon-centered carbonyl cluster Rh6C(CO)i5, (C) S 9(AsF6)2, and (B) the infinite and crystallo-graphically incommensurate mercury chains in Hg3, s(AsF6).
Such moieties are closely akin to the Hg2 -mesitylene structure in [Hg(C9Hi2)AlCl4]2 and presumably also to the (Hg2 )(C6H6)2 complexes in the structurally uncharacterized [Hg(C6H6)AlCl4]2. Thus, it seems that weak Hg-C bonds may help to stabilize the mercury chain clusters, an idea that is lent further support by the spectroscopic data of [Hg2(CO)2](Sb2Fn)2... [Pg.90]


See other pages where Mercury chains is mentioned: [Pg.523]    [Pg.523]    [Pg.523]    [Pg.523]    [Pg.524]    [Pg.524]    [Pg.524]    [Pg.524]    [Pg.525]    [Pg.525]    [Pg.526]    [Pg.526]    [Pg.27]    [Pg.176]    [Pg.1049]    [Pg.82]    [Pg.215]    [Pg.216]    [Pg.217]    [Pg.218]    [Pg.88]    [Pg.5922]    [Pg.90]    [Pg.25]   
See also in sourсe #XX -- [ Pg.2 , Pg.9 , Pg.12 , Pg.14 ]

See also in sourсe #XX -- [ Pg.2 , Pg.9 , Pg.12 ]




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