Melting deformation-induced

A tour of physical processes accessible in single-component water ice in experiments in a freezer ductile flow and deformation-induced melting and refreezing... 

A novel approach to flow- or deformation-induced crystallization entails the use of MC methods that have been developed to generate nonequUibrium ensembles of polymer melts that are characterized by some degree of anisotropy [133,135,136]. Recently,Baig and Edwards employed one of these methods to study crystallization of a UA model of C78 over a range of temperatures from 300 to 450 K, using a uniaxial flow field tensor whose values were estimated to mimic the behavior... 

First of all the term stress-induced crystallization includes crystallization occuring at any extensions or deformations both large and small (in the latter case, ECC are not formed and an ordinary oriented sample is obtained). In contrast, orientational crystallization is a crystallization that occurs at melt extensions corresponding to fi > when chains are considerably extended prior to crystallization and the formation of an intermediate oriented phase is followed by crystallization from the preoriented state. Hence, orientational crystallization proceeds in two steps the first step is the transition of the isotropic melt into the nematic phase (first-order transition of the order-disorder type) and the second involves crystallization with the formation of ECC from the nematic phase (second- or higher-order transition not related to the change in the symmetry elements of the system). 

In polymer processing, compaction is an important and necessary step in order to reduce the interparticle, unoccupied spaces and thus eliminate air. It is essential for melting in both single-screw extruders as well as for twin-rotor processors, as we shall see in Chapters 5 and 10. In twin-rotor devices, such as Co-TSEs, for example, the large and repeated deformation of compacted particulates by the kneading elements, which induces large plastic deformation of particulates, is the dominant melting mechanism. 

It was shown that the stress-induced orientational order is larger in a filled network than in an unfilled one [78]. Two effects explain this observation first, adsorption of network chains on filler particles leads to an increase of the effective crosslink density, and secondly, the microscopic deformation ratio differs from the macroscopic one, since part of the volume is occupied by solid filler particles. An important question for understanding the elastic properties of filled elastomeric systems, is to know to what extent the adsorption layer is affected by an external stress. Tong-time elastic relaxation and/or non-linearity in the elastic behaviour (Mullins effect, Payne effect) may be related to this question [79]. Just above the melting temperature Tm, it has been shown that local chain mobility in the adsorption layer decreases under stress, which may allow some elastic energy to be dissipated, (i.e., to relax). This may provide a mechanism for the reinforcement of filled PDMS networks [78]. 

In practice, many fabrication processes take place under non-isothermal, non-quiescent and high-pressure conditions. Mechanical deformation and pressure can enhance the crystallisation as well as the crystal morphology, by aligning the polymer chains. This leads to pressure-induced crystallisation and to flow-induced or stress-induced crystallisation, which in fact is the basis for fibre melt-spinning (see Sect. 19.4.1)... 

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