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Melezitose, hendecamethyl

The full methylation of melezitose in 1926-1927 by Zempldn and Braun and by Miss Leitch yielded a hendecamethyl-melezitose, the acid hydrolysis of which produced two moles of 2,3,4,6-tetramethyl-D-glucopyranose and one mole of a trimethyl-D-fructose, to which a 1,3,4-trimethyl structure was assigned on evidence that cannot now be regarded as precise, though it seemed reasonable at the time. The selection of a faulty formula for this trimethyl-D-fructose, which must have been 1,4,6-trimethyl-D-fructose as will be shown later, led to much confusion during the following decade. [Pg.20]


See other pages where Melezitose, hendecamethyl is mentioned: [Pg.37]    [Pg.47]    [Pg.92]    [Pg.30]   
See also in sourсe #XX -- [ Pg.20 ]

See also in sourсe #XX -- [ Pg.20 ]

See also in sourсe #XX -- [ Pg.20 ]




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