Mechanisms of replacement reactions

R. U. Lcmieux, Some implications in carbohydrate chemistry of theories relating to the mechanisms of replacement reactions, Adv. Carbohydr. Chem. Biochem 9 1 (1954). H. Tsu-tsumi and Y. Ishido, Syntheses of 1-O-acylaldose derivatives via the corresponding 0-glycosyI-pseudourcas, Carbohydr. Res. Ill 75 (1982). S. Horvat, L. Varga, and J. Horvat, A new utility of O-glycosylpseudoureas for synthesis of glucopeptides and (1— 6)-disaccharides, Synthesis 209 (1986). 

Lederer, E., Glycnlipids of Acid-fast Bacteria, 16, 207-238 Lemieux, R. U., Some Implications in Carbohydrate Chemistry of Theories Relating to the Mechanisms of Replacement Reactions, 9, 1-57 Lemieux, R, U., and Wolfrom, M. L., The Chemistry of Streptomycin, 3, 337-384... 

Some Implications in Carbohydrate Chemistry of Theories Relating to the Mechanisms of Replacement Reactions, R. U. Lemieux, Adv. Carbohydr. Chem., 9 (1954) 1-57. 

The life and work of one of the greatest carbohydrate scientists of our time, Raymond U. Lemieux, is recalled here in a sensitive account by Bundle (Edmonton). During a remarkably productive career extending over more than half a century, Lemieux pioneered the application of NMR spectroscopy in chemistry, developed rational approaches for glycosidic coupling, made major contributions to our understanding of three-dimensional carbohydrate structures and protein binding, and made important contributions in the biomedical area. His own articles in these Advances include the chemistry of streptomycin in Volume 3, the mechanisms of replacement reactions in Volume 9, and in Volume 50 a consideration of Emil Fischer s lock and key concept of enzyme specificity. 

SOME IMPLICATIONS IN CARBOHYDRATE CHEMISTRY OF THEORIES RELATING TO THE MECHANISMS OF REPLACEMENT REACTIONS... 

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