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Mechanism for transfer of Br+ from bromonium ion

Figure 2. Mechanism for transfer of Br from sym(collidine) bromonium ion to... Figure 2. Mechanism for transfer of Br from sym(collidine) bromonium ion to...
What concerns us here are three topics addressing the fates of bromonium ions in solution and details of the mechanism for the addition reaction. In what follows, we will discuss the x-ray structure of the world s only known stable bromonium ion, that of adamantylideneadamantane, (Ad-Ad, 1) and show that it is capable of an extremely rapid degenerate transfer of Br+ in solution to an acceptor olefin. Second, we will discuss the use of secondary a-deuterium kinetic isotope effects (DKie) in mechanistic studies of the addition of Br2 to various deuterated cyclohexenes 2,2. Finally, we will explore the possibility of whether a bromonium ion, generated in solution from the solvolysis of traAU -2-bromo-l-[(trifluoromethanesulfonyl)oxy]cyclohexane 4, can be captured by Br on the Br+ of the bromonium ion, thereby generating olefin and Br2. This process would be... [Pg.113]


See other pages where Mechanism for transfer of Br+ from bromonium ion is mentioned: [Pg.474]    [Pg.461]    [Pg.476]    [Pg.463]    [Pg.473]    [Pg.460]   
See also in sourсe #XX -- [ Pg.462 ]

See also in sourсe #XX -- [ Pg.462 ]




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