Theory and mechanism

Lowry, T.H. Richardson, K.S. Mechanism and Theory in Organic Chemistry Harper Row New York, 1976. 

See Yates, K. HUckel Molecular Orbital Theory Academic Press NY, 1978 Coulson, C.A. O Leary, B. Mallion, R.B. HUckel Theory for Organic Chemists Academic Press NY, 1978 Lowry, T.H. Richardson, K.S. Mechanism and Theory in Organic Chemistry, 3rd ed. Harper and Row NY, 1987, p. 100. 

Lowry and Richardson, Mechanism and Theory in Organic Chemistry , 3rd ed.. Harper and Row, New York, 1987. 

Wong, D.W.S., Colorants, in Mechanism and Theory in Food Chemistry, Avi Publishing, Westport, CT, 1989. 

Lowry TH, Richardson KS (1987) Mechanism and theory in organic chemistry, 3rd edn. Harper Collins, New York, Chapter 2... 

Addy Press s book, Theoretical and Physical Principles of Organic Reactivity, Wiley, New York, 1995, is an invaluable tool for understanding the way constructing a reaction profile can help the physical chemist to predict the outcome of a chemical reaction. Lowry and Richardson s Mechanism and Theory in Organic Chemistry (above) is also germane. 

The mechanisms and theories of chemical carcinogenesis are as follows (Powell and Berry, 2000 Williams and Iatropoulos, 2001) ... 

Sce Yates Hiickel Molecular Orbital Theory, Academic Press New York, 1978 Coulson O Leary Mallion Hiickel Theory for Organic Chemists. Academic Press New York, 1978 Lowry Richardson Mechanism and Theory in Organic Chemistry. 3rd ed.. Harper and Row New York, 1987. pp. 100-121. 

Arnett. E. M. J. Client. Educ. 1985.62,385-391. For a longer discussion than given here and more examples, see Lowry. T. H. RiclBidson, K. S. Mechanism and Theory in Organic Chemistry. 3rd e[Pg.717]

If these conditions are not satisfied, some process will be involved to prevent accumulation of the intermediates at the interface. Two possibilities are at hand, viz. transport by diffusion into the solution or adsorption at the electrode surface. In the literature, one can find general theories for such mechanisms and theories focussed to a specific electrode reaction, e.g. the hydrogen evolution reaction [125], the reduction of oxygen [126] and the anodic dissolution of metals like iron and nickel [94]. In this work, we will confine ourselves to outline the principles of the subject, treating only the example of two consecutive charge transfer processes O + n e = Z and Z 4- n2e — R. 

---