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Many-particle Hamiltonian symmetry property

For the two-electron integrals, we want to divide the integrals into symmetry classes, as for the nonrelativistic integrals. We also want to divide the integrals into classes by time reversal symmetry, as we did for the one-electron integrals. Because of the structure of the Kramers-restricted Hamiltonian in terms of the one- and two-particle Kramers replacement operators, we hope to obtain a reduction in the expression for the Hamiltonian from time-reversal symmetry. The classification by time-reversal properties is also important for the construction of the many-electron Hamiltonian matrix, whose symmetry properties we consider in the next section. [Pg.167]


See other pages where Many-particle Hamiltonian symmetry property is mentioned: [Pg.87]    [Pg.4]    [Pg.15]    [Pg.37]    [Pg.37]    [Pg.14]    [Pg.5]    [Pg.201]    [Pg.47]   
See also in sourсe #XX -- [ Pg.188 ]




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