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Manipulation of Phase-space Integrals

One way to reduce the problem slightly is to recognize that for many properties A, the position and momentum dependences of A are separable. In that case, Eq. (3.5) can be written as [Pg.81]

Since the Hamiltonian is also separable, the integrals in brackets on the r.h.s. of Eq. (3.31) may be simplified and we write [Pg.81]

Even with so large a simplification, however, the convergence of Eq. (3.32) for a realistically sized chemical system and a random selection of phase points is too slow to be useful. What is needed is a scheme to select important phase points in a biased fashion. [Pg.81]


See other pages where Manipulation of Phase-space Integrals is mentioned: [Pg.80]    [Pg.74]   


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