Manganous fluoride

Erickson, R. A. Neutron diffraction studies of antiferromagnetism in manganous fluoride and some isomorphons compounds. Phys. Rev. 90, 779 (1953). 

Manganic Fluoride, MnFg, mw 111.94, red, poisonous crysts, sp gr 3-54 mp — decomp on heating sol in acids decomp by w. Can be prepd by dissolving Mn in dil HF contd in a silver basin (Ref 2) and by other methods. Used as a Guorinating agent Refs 1) Gmelin-Kraut, not found 2) Mellor 12(1932), 342 3) CondChemDict (1961),... 

Ammino-manganous Fluoride.—Manganous fluoride is sparingly soluble in liquid ammonia, a crystalline powder being formed which is probably the sesquiammine, [Mn3(NH3)2]F6. It slowly evolves ammonia, and when heated to a temperature of 1200° C. in an atmosphere of ammonia the fluoride is partially reduced.1... 

STO/CAT] Stout, J. W., Catalano, E., Heat capacity of zinc fluoride from 11 to 300 K. Thermodynamic functions of zinc fluoride. Entropy and heat capacity associated with the antiferromagnetic ordering of manganous fluoride, ferrous fluoride, cobaltous fluoride, and nickelous fluoride., J. Chem. Phys., 23, (1955), 2013-2022. Cited on pages 119,283. 

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