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Manganese complexes with silyl ligands

The particular chemical behavior of hydridosilyl-manganese complex 166, which contrasts sharply with that of hydridosilyl-iron complexes (12,252), has been interpreted in terms of a bonding interaction between hydrido and silyl ligands this is detailed in Sect. IV-B-3 in connection with hydrosilylation processes. [Pg.147]

As regards the similarity with simple coordination of two-electron ligands, it is of interest to discuss the oxidative addition of silicon hybrid to methyl cyclopentadienyl-manganese carbonyl and the nature of the bonding in the adduct. Hydrido silyl-manganese complexes were first prepared by Jetz and Graham according to... [Pg.325]


See other pages where Manganese complexes with silyl ligands is mentioned: [Pg.241]    [Pg.171]    [Pg.241]    [Pg.128]    [Pg.158]    [Pg.356]    [Pg.357]    [Pg.1443]    [Pg.1443]    [Pg.187]    [Pg.270]    [Pg.524]    [Pg.2069]    [Pg.254]    [Pg.296]    [Pg.2069]    [Pg.404]   
See also in sourсe #XX -- [ Pg.255 ]




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Complexes silyls

Complexes with //-ligands

Ligand manganese complexes with

Manganese complexes

Manganese complexes, with

Manganese complexing

Manganese ligands

Manganese silyl complexes

Silyl complexes

Silyl ligands

With manganese

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