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Manganese carbonyls, exchange reactions

Investigations of racemization and ligand exchange reactions of manganese complexes [Mn(7j -C5H4R)L L L ] have continued and more evidence to support a dissociative mechanism with a chiral three-co-ordinate intermediate has been obtained. Reaction (1) is so slow that chiral four-co-ordinate alkyl intermediates formed by carbonyl... [Pg.434]


See other pages where Manganese carbonyls, exchange reactions is mentioned: [Pg.48]    [Pg.299]    [Pg.57]    [Pg.289]    [Pg.48]    [Pg.219]    [Pg.156]    [Pg.25]    [Pg.139]    [Pg.308]    [Pg.139]    [Pg.123]    [Pg.108]    [Pg.439]    [Pg.192]    [Pg.732]   
See also in sourсe #XX -- [ Pg.28 , Pg.32 , Pg.33 , Pg.35 , Pg.38 , Pg.39 ]




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