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Manganese carbonyl derivatives substitution

Although complexes of various coordination numbers have been studied, those with an octahedral metal atom, including substituted Group VI carbonyls and manganese carbonyl halides and their derivatives, have been... [Pg.189]

In contrast to the behavior of the manganese derivative (LXVIII), the iron compound undergoes carbonyl substitution without cleavage of the Si-M bond (entry 7). [Pg.101]

Reactions with Carbonyl Compounds Followed by Insertion Reactions. IV-Substituted -aminoketones react with TMSC(Li)N2 to give 2-pyrroUne derivatives via the alkylidene carbene intermediates by intramolecular N-H insertion, analogously to the reaction of -acyl-A(-tosylanilines with TMSC(Li)N2 (eq 21). Dehydrogenation of the 2-pyrrolines with active Mn02 (CMD, chemical manganese dioxide, produced for battery manufacture) affords the corresponding pyrroles (eq 24). ... [Pg.194]

See other pages where Manganese carbonyl derivatives substitution is mentioned: [Pg.90]    [Pg.139]    [Pg.2523]    [Pg.2522]    [Pg.108]    [Pg.206]    [Pg.217]    [Pg.201]    [Pg.192]    [Pg.213]    [Pg.218]    [Pg.119]    [Pg.166]    [Pg.141]    [Pg.29]    [Pg.1]    [Pg.25]    [Pg.277]    [Pg.230]    [Pg.23]    [Pg.276]    [Pg.355]    [Pg.155]    [Pg.80]    [Pg.313]    [Pg.119]    [Pg.9]    [Pg.121]    [Pg.177]    [Pg.151]    [Pg.250]    [Pg.120]    [Pg.377]    [Pg.216]    [Pg.187]   
See also in sourсe #XX -- [ Pg.219 ]



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Carbonyl derivatives

Carbonyl substitution

Carbonylation derivatives

Carbonylation substitutive

Carbonylation, manganese

Manganese carbonyl carbonylation

Manganese carbonyls

Manganese derivatives

Substituted derivatives

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