Maleated epoxidized oils

One of the current active research areas is green chemistry and sustainability. As part of this thrust, there has been a fair amount of research interest in soybean oil and its derivatives. Soybean oil (SBO) (/) is cheap, easily available, renewable, and environmentally friendly. Some examples of SBO derivatives are epoxidized oil (2), SBO methyl ester (methyl soyate) (5), maleated products (4), SBO polymers (5), and others (5). This area of research has been reviewed 5a, 7). 

COMPOUND NAME, PAGE Activator OT Urea, 37 Markstat 51,263 Markstat 51,264 Markstat 51,265 Cyanox STDP, 81 Cyanox LTDP, 79 Stearic Acid, 313 Polycizer Butyl Oleate, 287 Butyl ricinoleate, 195 Flexol EP-8, 231 Flexol EP-8, 233 Flexol EP-8, 232 Epoxidized linseed oil, 229 Epoxidized linseed oil, 227 Epoxidized linseed oil, 228 Cure-Rite IBT, 35 Dioctyl maleate, 223 Isonox 232, 111 Ethaphos 368, 95 Alkanox P27, 63 Kemamide E ultra, 309 Citroflex B-6, 209 Laurex , 261 Retarder AK, 311 Santicizer 278, 155 Perkacit DPG, 305... 

Epoxy resin adhesives for aluminum, glass, and steel have been prepared by converting octaallyl or octacrotyl-sucrose to the corresponding epoxides which were cured with diethylenetriamine.157 Several plastics, resins, and adhesives have been based on soybean oil.158 Vinyl esters of the fatty acids can be used as monomers. The oil can be epoxidized, then hydrolyzed to glycols, which can be converted to acrylates or maleates for polymerization. Natural fibers, such as hemp, can be used with such materials to form inexpensive composites. 

Esen, H., Kusefoglu, S. and Wool, R. (2007) Photolytic and free-radical polymerization of monomethyl maleate esters of epoxidized plant oil triglycerides. Journal cf Applied Polymer Science, 103(1), 626-633. Ozturk, C. and Kusefoglu, S.H. (2010) Polymerization of epoxidized soybean oil with maleinized soybean oil and maleic anhydride grafted polypropylene mixtures. Journal cf Applied Polymer Science, 118(6), 3311-3317. 

Estabex 138-A, Estabex 2307 DEOD, Estabex 2307. See Epoxidized soybean oil, Estabex 2381. See 2-Ethylhexyl epoxystearate, Estaflex ATC. See Acetyl tributyl citrate Estalan 12. See Laureth-2 octanoate Estalan 38, Estalan 42. See Laureth-2 acetate Estalan 126. See Laureth-2 benzoate Estalan 430. See Diethylene glycol dioctanoate/diisononanoate Estalan 718. See Octyl hydroxystearate Estalan 816. See Octyl palmitate Estalan CM. See Cetyl myristate Estalan CP. See Cetyl palmitate Estalan CSO. See Cetearyl octanoate Estalan DIA. See Diisopropyl adipate Estalan-DID. See Diisopropyl dimer dilinoleate Estalan-DIPS. See Diisopropyl sebacate Estalan DISD. See Diisostearyl dimer dilinoleate Estalan-DISM. See Diisostearyl malate Estalan DNPA. See Dipropyl adipate Estalan DO. See Decyl oleate Estalan DOM, Estalan-DOMA. See Dioctyl maleate... 

H. Esen, S. Kusefoglu and R. Wool, Photolytic and free-radical polymerization of monomethyl maleate esters of epoxidized plant oil triglycerides , / Appl Polym Sci, 2007,103, 626-33. 

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