Malaprade Reactions mechanism

The cleavage of 1,2-diols 1 by periodic acid is associated with the name of the French chemist Malaprade. The reaction mechanism is related to that outlined above, and is likely to involve a five-membered ring periodate ester intermediate 7 ... [Pg.138]

The method was used in the study of the mechanism of the Malaprade reaction, and for the estimation of the number... [Pg.144]

We emphasize that it is only a trick of writing and is in no case a reactional mechanism. Malaprade s reaction is interesting for the determination of sugars and polyols. [Pg.363]

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