Magnetic of lanthanides

The L and S values are those from which the / value was formed via the vector coupling rule. These formulae strictly apply only for the magnetism of free-ion levels. They provide a good aproximation for the magnetism of lanthanide complexes, as we shall note in Chapter 10, but provide no useful account of the magnetic properties of d block compounds. [Pg.87]

Benelli, C. and Gatteschi, D. (2002) Magnetism of lanthanides in molecular materials widi transition-metal ions and organic radicals. Chemical Reviews, 102, 2369-2387. [Pg.272]

The standard approach to describing the magnetism of lanthanides, and in particular their magnetic moments, is to assume the picture of electrons in an... [Pg.8]

Local Structure of the Eu2+ Impurity. From the experimental perspective, the doping of lanthanide ions into solid state materials can be probed by different instrumental technics such as nuclear magnetic resonance (NMR),44 extended X-ray absorption fine structure (EXAFS),45,46 or electron paramagnetic resonance (EPR),47 which instead of giving a direct clue of the local geometry offers only data that can be corroborated to it. From the theoretical point of view,... [Pg.2]

Electronic Structure and Magnetic Properties of Lanthanide Molecular Complexes... [Pg.3]

Modelling the Magnetic Properties of Lanthanide Single-Ion Magnets 29... [Pg.30]

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