Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Magnesium 2,2,6,6-tetramethylpiperidide

Among other reagents that effect epoxide ring opening are diethylaluminum 2,2,6,6-tetramethylpiperidide and magnesium (V-cyclohexyl-A-O -propy amide. [Pg.1115]

The magnesium bis(amide) Mg(TMP)2 (TMP = 2,2,6,6-tetramethylpiperidide) has been shown to be a useful base in the selective deprotonation of arenes to produce aryhnagne-sium amide intermediates . For example, reaction of Mg(TMP)2 with methyl benzoate... [Pg.419]

Preparative Methods prepared in situ by lithiation of trimethylsi-lyldiazomethane using n-butyllithium prepared in situ by lithiation of trimethylsilyldiazomethane (TMSCHN2) using butyllithium, lithium diisopopylamide (LDA), or lithium 2,2,6,6-tetramethylpiperidide (LTMP). The lithium salt is easily converted to the corresponding magnesium bromide salt (eq 1). [Pg.191]

See other pages where Magnesium 2,2,6,6-tetramethylpiperidide is mentioned: [Pg.284]    [Pg.197]    [Pg.27]    [Pg.157]    [Pg.41]    [Pg.45]    [Pg.49]    [Pg.49]    [Pg.45]    [Pg.49]    [Pg.49]    [Pg.1277]    [Pg.63]    [Pg.67]    [Pg.144]    [Pg.284]    [Pg.105]    [Pg.12]    [Pg.22]    [Pg.129]   
See also in sourсe #XX -- [ Pg.284 ]



SEARCH



2,2,6,6-tetramethylpiperidide

© 2024 chempedia.info