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Magnesium Inverse Crown Complexes

Hydride encapsulation in inverse crown molecules has also been observed. The reaction of NaBu, MgBu2 and three equivalents of HNPr 2 led to [Na2Mg2(NPr 2)4(p-H)2] which [Pg.57]

Scheme 3.9 A selection of magnesium amide-based inverse crown complexes ... Scheme 3.9 A selection of magnesium amide-based inverse crown complexes ...
BaiUie SE, Blair VL, HeviaE, Kennedy AR. A new polymeric alkyl/alkoxide magnesium-sodium inverse crown complex. Acta Crystallogr C. 2011 67(7) m249-m251. [Pg.44]

The first alkaline earth metal inverse crowns were discovered in the late 1990s via the fortuitous reaction of traces of O2 with a mixture of an alkali metal and a magnesium amide to afford complexes of e formulae (see Scheme 3.9) M2Mg2 N(SiMe3)2 4(O2)x(O)... [Pg.57]

See other pages where Magnesium Inverse Crown Complexes is mentioned: [Pg.56]    [Pg.56]    [Pg.94]    [Pg.16]    [Pg.399]    [Pg.18]    [Pg.57]    [Pg.129]    [Pg.178]   


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