Lutetium chloro

Metathetical routes using bulky lithium guanidinates as starting materials have also been employed to synthesize bis(guanidinato) lanthanide halides as well as reactive alkyls and hydrides. Scheme 63 shows as a typical example the formation of the lutetium chloro precursor, which was isolated in 76% yield. ... 

Li5H7KaiO, ,P,W4,92H2O, Octatetracon-tatungstooctaphosphate(40-), pentali-thium octacosapotassium heptahydro-gen, dononacontahydrate, 27 110 LuCIOCi H,6, Lutetium, chloro(T] -l,3,5,7-cyclooctatetraene) (tetrahydrofuran)-, 27 152... 

CILi, Lithium chloride. 28 322 QLuOC,2H,4, Lutetium, chloro(i -13,S,7-( dooctatetraene) (tetrahydiofuran)-, 27 152... 

Chloro 8 l,3,5,7-cyclooctatetraene)(tetrahydrofuran)lutetium, 3530 Chloroiodoethyne, see Chloroiodoacetylene, 0595 3-Chloro-l-iodopropyne, 1070... 

Cl2Lu2Si4C44HM, Lutetium, tetrakis t) -l,3-bis(trimethylsilyl)cyclopentadienyl]di-p.-chloro-di-, 27 171... 

The hydroxo complexes (3a)2Ho(OH) and (3a)2Er-(OH), reported by C. Qian et al., were formed from the respective chloro complex and trace amounts of water present in the solvent. The lutetium analogue has been suggested as the final product of the hydrolysis of (3a)2LuCl, which was investigated by IR spectroscopy. The related yttrium compound 9aY(OH) was obtained by H. Schumann et al. from... 

---