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Lithium pentamethylcyclopentadienide

Caution. Both lithium pentamethylcyclopentadienide and 1 are extremely air sensitive and should be handled using high-vacuum line and inert atmosphere glove box techniques. [Pg.43]

The Cobalt Triad.— The first methylene-bridged binuclear cobalt complex [Ck)2O-CO)0i-CH2)(C5Mes)2] has been obtained by treatment of C0CI2 with lithium pentamethylcyclopentadienide and the lithium enolate of acetaldehyde (Li+CHaCHO-). The novel transannular electron-rich olefin (35) reacts with f RhCl(cod) 2] to form the chelating c -dicarbenerhodium(i) salt (36) [X=RhCla-... [Pg.240]

Reaction of dichloro(pentamethylcyclopentadienyl)silane with lithium, sodium or potassium naphthalenide gives a mixture of elemental silicon, the corresponding alkali metal pentamethylcyclopentadienide and decamethylsilicocene (82) (equation 64)181. Compound 82 is formed as the only product in the reduction of dibromo-bis(pentamethylcyclopentadienyl)silane with potassium anthracenide (equation 65)182. [Pg.2163]

See other pages where Lithium pentamethylcyclopentadienide is mentioned: [Pg.403]    [Pg.368]    [Pg.3367]    [Pg.3366]    [Pg.641]    [Pg.641]    [Pg.470]    [Pg.403]    [Pg.368]    [Pg.3367]    [Pg.3366]    [Pg.641]    [Pg.641]    [Pg.470]   
See also in sourсe #XX -- [ Pg.368 ]



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