Lithium 2-dimethylaminoethoxide

Whereas dibutylboron enolates may be used as specific enolates in aldol condensations, their reactions with alkyl halides are relatively poor. However, the addition of one equivalent of lithium 2-dimethylaminoethoxide results in site-specific mono-a-alkylation in excellent yield. Organotin enamines add to electrophilic alkenes such as acrylonitrile. The use of an optically active... 

Lithium dimethylaminoethoxide, (CH3)2NCH2CH2OLi (1). The alkoxide is generated from 2-(dimcthylamino)ethanol with CH3Li. 

Lithium 4,4 -di-r-butylbiphenyl, 240 Lithium diisopropylamide, 241-243 Lithium dimethylaminoethoxide, 244 Lithium l-(dimethylamino)naphthalenide, 244-245... 

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See also in sourсe #XX -- [ ]

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