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Lithium aluminum hydride demercurations

Preparative Methods three methods of preparation have been reported (a) from the treatment of ethyl bromoacetate with zinc followed by the reaction with chlorotrimethylsUane and subsequent reduction of the resultant ethyl trimethylsUylacetate with lithium aluminum hydride or borane-tetrahydrofuran (eq 1) (b) from the hydroboration/oxidation or oxymercu-ration/ demercuration of vinyltrimethylsUane (eq 2) and (c) most conveniently, by the reaction of the Grignard reagent formed from (chloromethyl)trimethylsilane with paraformaldehyde (eq 3). ... [Pg.622]

See other pages where Lithium aluminum hydride demercurations is mentioned: [Pg.72]    [Pg.2013]    [Pg.62]    [Pg.80]   
See also in sourсe #XX -- [ Pg.851 ]

See also in sourсe #XX -- [ Pg.8 ]

See also in sourсe #XX -- [ Pg.8 ]



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Demercuration

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