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Lithiation of Dichloromethane

LiCHCl2 + PhCH—O TiiF PhCH(OH)CHCl2 (after hydrolysis) LiCHCl2 + C8H17Br THF heitane HMPT C8H17CHC12 + LiBr [Pg.176]

With BuLi in a mixture of EtaO and hexane the metallation is very slow at — 95 °C. Above — 80 °C metallation and decomposition (of the carbenoid) proceed at comparable rates. [Pg.177]

Villieras J, Pierot P, Normant JF (1977) Bull Soc Chim France 765 [Pg.177]


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Dichloromethane

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