Liquids in pores

However, the influence of the attraction, exerted by the pore wall on the adsorptive, also plays a role and in more detailed interpretations, this should be taken into account. An illustration that liquids in capillaries may behave differently from their bulk counterpart is given in fig. 1.39. With increasing temperature, the hysteresis loops become thinner, disappearing completely at T=0.94 Tprif, i.e. the critical point of liquid in pores is lower than that of bulk liquid. 

Gomez, F., Denoyel, R., and Rouquerol,]. (2000). Determining the contact angle of a nonwetting liquid in pores by liquid intrusion calorimetry. Langmuir, 16, 4374—9. 

Transient equations of conservation of mass for the gas and the liquid in pores are same as Eqns. (1) and (3) both for Case I and Case II. 

TJ[R) is the melting temperature of a frozen liquid in pores of radius R is the bulk melting temperature p is the density of the solid... 

R. Prasad, S. Khare, A. Sengupta, and K. K. Sirkar, Novel liquid-in-pore configurations... 

Pressure distribution in liquid in pores of plate drying by evaporation from both faces, calculated from Eq. 18 for several values of the parameter a. 

Filled volatile liquid in pores is evaporated over time mass change over time is measured and relates to vapor pressure Observes membrane morphology directly... 

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