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Liquids phase structures

Assuming that phosgene packs as a cubic molecule with cube sides equal to its diameter, then (from density data) its effective molecular radius in the liquid state is 0.245 nm [1129]. [Pg.311]


Liquid Phase Structural Control of Mono- and Bimetallic Nanoparticles... [Pg.361]

In the isoelectronic B3H7 LB species, the liquid phase structure (VII-A13) is definitely indicated to be correct by Parry and Paine 39, 109), rather than a structure with elements of both VII-A13 and II-A13 which may be more stable in the crystal phase 97). [Pg.117]

Due to the fact that most chloroaluminate ILs comprise a mixture of species, much of the early NMR work of and in ILs was focused on speciation and on investigating the liquid-phase structure of fhese liquids. [Pg.358]

Among the most important topics that are frequently addressed via NMR spectroscopy are questions about the structure of a chemical compound. Thus, it is not surprizing that the liquid-phase structure of many common ILs has been investigated using NMR techniques. [Pg.265]

Fig. 8 Liquid-phase structure of [omim]Br in H20 as proposed by Zhao and co-workers. Black balls = Br gray balls = D20. Reprinted with permission from [44]. Copyright 2008 American Chemical Society... Fig. 8 Liquid-phase structure of [omim]Br in H20 as proposed by Zhao and co-workers. Black balls = Br gray balls = D20. Reprinted with permission from [44]. Copyright 2008 American Chemical Society...
The primary problem of chemical kinetics is the formulation of an empirical rate law which represents the rate of a reaction as a function of the concentrations or partial pressures of reactants, products, and catalysts present in a gaseous or liquid phase, structure and composition of solid catalysts, temperature, etc. A secondary problem is the ascertainment of the mechanism, which is often represented by a sequence of consecutive steps, or several sequences in parallel. The knowledge of the mechanism of a reaction in turn may be used in order to formulate a rational rate law which may represent the empirical rate data in a more logical form than an empirical rate law. [Pg.375]

Glass, R. J. Nicholl, M. J. Rajaram, H. Wood, T. R. Unsaturated Flow through Fracture Networks Evolution of Liquid Phase Structure, Dynamics, and the Critical In ortance of Fracture Intersections. Water Resour. Res. 2003.39(12), 1352. [Pg.225]

Many studies of biomolecules carried out by ESI-MS assume that, in the gas-phase conditions, ions retain elements of liquid-phase structures [22]. This assumption is supported by experimental results and molecular dynamics simulations. It has been suggested that solution-phase conformers of some proteins may be preserved for several tens of milliseconds after the ESI [21, 23, 24]. Because of the soft character ofESI, some protein-ligand complexes and large protein assemblies may also maintain non-covalent bonding in the gas phase [16, 24-29]. For example, nanospray electrospray ionization (nanoESI)-MS enabled the formation of complexes between a heat shock protein and an unfolding luciferase (client) to be monitored in the course of a few minutes [30]. [Pg.293]

Xian ZX, Kass SR (2009) Gas-phase versus liquid-phase structures by electrospray ionization mass spectrometry. Angew Chem Int Ed 48 1321-1323... [Pg.222]

Xian ZX, Kass SR (2008) Does electrospray ionization produce gas-phase or liquid-phase structures J Am Chem Soc 130 10842-10843... [Pg.222]


See other pages where Liquids phase structures is mentioned: [Pg.363]    [Pg.365]    [Pg.57]    [Pg.120]    [Pg.170]    [Pg.167]    [Pg.269]    [Pg.15]    [Pg.164]    [Pg.265]    [Pg.273]    [Pg.311]    [Pg.41]    [Pg.112]    [Pg.157]    [Pg.306]    [Pg.104]    [Pg.643]    [Pg.519]    [Pg.144]    [Pg.158]    [Pg.105]    [Pg.112]    [Pg.49]   
See also in sourсe #XX -- [ Pg.311 ]




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Liquid structure

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