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Ligand Group 13 diyls

TRANSITION METAL COMPLEXES WITH GROUP-13 DIYL LIGANDS ER (E = B, Al, Ga, In, Tl)... [Pg.216]

Table 7.12 Calculated BDEs De (Do) (kcal/mol) of iron carbonyl complexes with group-13 diyl ligands ER (E = B - Tl).a... Table 7.12 Calculated BDEs De (Do) (kcal/mol) of iron carbonyl complexes with group-13 diyl ligands ER (E = B - Tl).a...
Besides BINAP or p-TolBINAP, optically active peraryldiphosphines with axial chirality based on the biphenyl groups (6,6 -dimethylbiphenyl-2,2 -diyl)bis(diphenylphosphine) and its analog are also effective ligands for the asymmetric isomerization as expected [21],... [Pg.160]

Another often used chiral ligand is l,F-binaphthyl-2,2 -diyl-bis(phosphine), or binap.It can be built into ruthenium catalysts, which display high activities and enantio-selectivities for the hydrogenation of alkenes, amines, allylalcohols, and unsaturated carbonyls. A directing effect is observed for an a-hydroxy group in these cases. [Pg.1333]

The group-13 diyl complexes are an example where quantum chemical studies determined the understanding of the metal-ligand bonding situation since the very first compound of the new class of molecules (CO)4Fe-AlCp was isolated and characterized by X-ray structure analysis [93]. The TM-ER bonding situation can be qualitatively... [Pg.332]

Complexes of titanium with chelating diyl ligands represent a large group, for example. [Pg.230]

See other pages where Ligand Group 13 diyls is mentioned: [Pg.512]    [Pg.565]    [Pg.207]    [Pg.216]    [Pg.219]    [Pg.220]    [Pg.144]    [Pg.184]    [Pg.445]    [Pg.263]    [Pg.363]    [Pg.363]    [Pg.793]    [Pg.413]    [Pg.5835]    [Pg.133]    [Pg.240]    [Pg.216]    [Pg.228]    [Pg.166]    [Pg.88]    [Pg.282]    [Pg.8]    [Pg.338]    [Pg.340]    [Pg.358]    [Pg.132]    [Pg.72]    [Pg.177]    [Pg.193]    [Pg.357]    [Pg.90]    [Pg.24]    [Pg.30]    [Pg.195]    [Pg.341]    [Pg.305]    [Pg.30]    [Pg.279]    [Pg.299]    [Pg.199]    [Pg.8]    [Pg.419]   
See also in sourсe #XX -- [ Pg.471 ]



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Diyls

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Ligand groups

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