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Ligand field spectra electronic properties

The electronic spectrum is yet another property which illustrates the similarities between the metallocenes and (7r-ollyl) metal compounds. In Table VI are listed some data for a series of Coin(absorption bands with the small extinction coefficients are probably two of the spin-allowed d-d transitions. Scott (34) has developed an approximate axial ligand field model for the carborane-transition metal complexes and has discussed the optical spectra in relation to this bonding theory. The actual assessment of bonding in the (7r-ollyl) metal compound as well as the metallocenes would be greatly aided by accurate assignments of the electronic spectra. [Pg.108]

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See also in sourсe #XX -- [ Pg.160 , Pg.161 , Pg.162 , Pg.163 ]



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