Ligand arrangement

Cobalt(III) contains six 3d electrons in the presence of six appropriate ligands, arranged octahedrally, a large splitting of the d... 

Table 7.9 Symmetry species of orbitals resulting from the splitting of d orbitals by various ligand arrangements...

Table 7.10 shows how a ligand orbitals are elassified in various point groups with different ligand arrangements. It shows that, in oetahedral MLg, the six a ligand orbitals are split into aig,Sg and t-effeet of these on the e... 

Table 6.3 Ligand arrangement and structural properties in reported niobium oxychloride cluster compounds.

Relationships Between Ligand Arrangement and Direct Inter-cluster Linkages... 

The ligand arrangement in these oxychlorides leads to equivalent coordination of all niobium atoms, which correlates with the formation of structures containing discrete clusters. 

Relationships Between the Ligand Arrangement and Inter-cluster Linkages via Counter-ions... 

Fig. 6.10 Examples of the directional effect of oxide ligand arrangement on the location of hard cations and orientation of M-O linkages.

An alternative mechanism that has been suggested [93, 118] for the intersystem crossing process is based on a twist movement of the octahedral ligand arrangement. Two modes designated by M 3 and Ml and illustrated in Fig. 13... 

Table 7. Coordination numbers of important tin(II)-ligand arrangements...

No ionic species with this special ligand arrangement around the tin atom has been reported so far. 

In Section 3.2.1 we have deduced the dependence of the geometries of tin-ligand arrangements on the coordination number. We will now study the distances between the tin(II) atom and the ligand when the coordination number is changed. In Tables 8-11 the mean distances between the central tin atom and four different ligands (N, O, F and S) are listed. As expected, these distances increase with rising... 

Figure 5.2 Ligand arrangements about a central nucleus...

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