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LiAlH4, reaction with aryl halides

Reduction of aryl and alkyl halides.5 This reaction can be conducted in generally good yield with LiAlH4 by a free-radical process initiated by irradiation of di-r-butyl peroxide. The order of reactivity of aryl halides is Arl > ArBr > ArCl > ArF. Alkyl and cycloalkyl halides are reduced efficiently, but vinyl bromides are reduced in only modest yield. [Pg.275]

See other pages where LiAlH4, reaction with aryl halides is mentioned: [Pg.81] [Pg.165] [Pg.521] [Pg.150] [Pg.318] [Pg.89] [Pg.276] [Pg.89] [Pg.116] [Pg.343] [Pg.435] [Pg.297] [Pg.13]

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Aryl halides reactions

Aryl halides, reaction with

Halides, aryl, arylation reaction

With aryl halides