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Lanthanoid trichlorides

Fujiwara and coworkers" have discovered that anhydrous lanthanoid trichloride salts are reusable Friedel-Crafts catalysts for the benzylation of benzene. All of the lanthanoid trichlorides offer fairly good yields of benzylated product (equation 15). The yields do not drop if the recovered catalyst is used for a second time, or in some cases even a third time, for the benzylation of benzene. [Pg.302]

Neutral homoleptic allyl complexes of lanthanoids apparently are not prepared till now. However, bimetallic complexes of the ar -type Li2Ln(r -C3H5)5(diox)n have been synthesized for most lanthanoids [3, 4, 5, 6, 7]. They are formed in the reaction of anhydrous trichlorides of lanthanoids with five equivalents of allyllithium ... [Pg.122]

See other pages where Lanthanoid trichlorides is mentioned: [Pg.211]    [Pg.213]    [Pg.218]    [Pg.2]    [Pg.211]    [Pg.213]    [Pg.218]    [Pg.2]    [Pg.27]    [Pg.125]    [Pg.194]    [Pg.1013]    [Pg.182]    [Pg.278]   


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Lanthanoid trichlorides Friedel-Crafts catalysts

Lanthanoid trichlorides benzylation of benzene

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