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Lanthanide, Yttrium, and Scandium

Lanthanide, yttrium and scandium trihalides preparation of anhydrous materials and solution thermochemistry. J. Burgess and J. Kijowski, Adv. Inorg. Chem. Radiochem., 1981, 24, 57-114, (320). [Pg.27]

LANTHANIDE, YTTRIUM, AND SCANDIUM TRIHALIDES PREPARATION OF ANHYDROUS MATERIALS AND SOLUTION THERMOCHEMISTRY... [Pg.66]

In addition to lanthanides, yttrium and scandium salts, which appear in the same column of Mendelejew periodic table, were also shown to act as Lewis acid... [Pg.312]

The authors determined mononuclear hydrolysis constants logn, j (Th(OH) ) and logjo (Th(OH)2 ) in water and in aqueous ethanol mixtures containing 19.8 and 40.3 mass% ethanol at / = 0.05 M and 25°C. Similar measurements were made for the trivalent lanthanide, yttrium, and scandium ions, which do not concern this review. Usherenko and Skorik [1972USH/SKO] observed a linear relationship between logic A°i (Th(OH) ) and the reciprocal of the dielectric constant of the solvent. [Pg.535]

The primary aim of this review is to collect together information on the solution thermochemistry of the trihalides of the lanthanides, yttrium, and scandium. There is a meager amount of published work relating to nonaqueous solvents, rather more relating to aqueous solu-... [Pg.57]

Fluorides of the lanthanides, yttrium, and scandium normally precipitate from aqueous media as the hemihydrates, LnFa- HjO. It is these hemihydrates which are in equilibrium with saturated solution, and the solubility-product measurements refer to these hemihydrates. [Pg.84]


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