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Lanthanide tris tetramethylaluminate

Scheme 58 Synthesis of homoleptic lanthanide tris(tetramethylaluminate) complexes Ln[(/x-Me)2AlMe2]3 (Ln = Y, La, Ce, Pr, Nd, Sm, Gd, Lu)... Scheme 58 Synthesis of homoleptic lanthanide tris(tetramethylaluminate) complexes Ln[(/x-Me)2AlMe2]3 (Ln = Y, La, Ce, Pr, Nd, Sm, Gd, Lu)...
Preformation of homoleptic lanthanide tris(tetramethylaluminate) complexes Ln(AlMe4)3 (Ln = Y, La, Ce, Pr, Nd, Sm, Gd) and Et2AlCl generated extremely active and highly cis-1,4-slcrcosclective binary diene polymerization initiators (Fischbach et al., 2006, personal communication) [150]. Optimal performance in isoprene polymerization was observed for most of the lanthanide metal centers for (Cl) (Ln) ratios of 2 1 (Table 16). Only the samarium... [Pg.228]

See other pages where Lanthanide tris tetramethylaluminate is mentioned: [Pg.216]    [Pg.216]    [Pg.230]   
See also in sourсe #XX -- [ Pg.216 ]



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Tetramethylaluminates

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