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Landau-Zener crossing formalism Borgis-Hynes model

On the basis of a Landau-Zener curve crossing formalism, Borgis and Hynes derived the nonadiabatic rate constant k, which is similar to that expressed by the DKL model but where the tunneling term Cnm found in Eq. (4) is significantly modified due to the influence of the low-frequency promoting mode Q, with a frequency 0)q, on the tunneling rate. The dependence of Cnm on Q is given by [13]... [Pg.77]


See also in sourсe #XX -- [ Pg.66 ]

See also in sourсe #XX -- [ Pg.66 ]

See also in sourсe #XX -- [ Pg.66 ]




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