L- aziridine

Primary allyUc amines.l Aziridines can be converted into allyl carbamates by reaction with ethyl chloroformate to form N-ethoxycarbonylaziridines followed by thermolysis in benzene at 200-250°. Rearrangement of trisubstituted ethoxycarbonylaziridines is regiospecific. 

TRIS(ALLYLOXY)TRLAZINE see THN500 TRIS(AMINOETHYL)AMINE see NEI800 TRIS( -AMINOETHYL)AMINE see NEI800 TRIS(l-AZIRIDINE)PHOSPHINE OXIDE see TND250... 

IH-Aziridines. In the presence of BF3 etherate, this reagent adds to double bonds substituted with three cyano or carboalkoxy groups to give an adduct that is converted into a l//-aziridine by treatment with triethylamine. 

S),25-epiminolanosterol (116) was a potent noncompetitive inhibitor (Kj = 3.0 nM) of the 5-adenosyl-L-methi(Miine-C-24 Me transferase from sunflower embryos [127]. Cholesteryl ester of l-aziridine acetic acid (117) showed excellent inhibition of a dimethyl-benzanthrene induced and transplantable mammary adenocarcinoma [128]. 

CgHsNHNH, (CgH,)2N-N(CgHg)2 N-A minopheny l-aziridine Girard reagents Tosylhydrazine Benzalazine HN.NH... 

The photoirradiation of l-(2-naphthc l)aziridine in halogenated hydrocarbon solvents gave a canplex mixture of products amongst vhich... 

---