L-acofriose

D-Oleandrose (38) has so far only been isolated from the digitanol glycoside lanafolein, but never from a cardenolide. With the exception of L-acofriose (27), L-acovenose (31), and L-diginose (42), all of these sugars have been prepared synthetically. A glycoside from Beaummtia grandiflora contains L-cymarose, which was recently obtained crystalline. 

All the 6-deoxyhexoses and all the methyl ethers found in these substances, except L-acofriose (27) and L-acovenose (31), have been synthesized. L-Acofriose (27) was first obtained by Hirst and Dunstan from... 

A sugar component isolated from the lipopolysaccharide from Rh. capsulata was shown by m.s. (as its alditol acetate) to be a 6-deoxy-3-O-methylhexose. From its chromatographic mobilities and optical rotation, it was shown to be identical with 3-O-methyl-L-rhamnose (l-acofriose)... 

A number of 6-deoxyhexoses also are widespread in plants, but these compounds are especially common in cardiac glycosides (Courtois and Percheron, 1970). These sugars are formed from the corresponding hydroxylated monosaccharides (Luckner, 1990). Among the 6-deoxyhexoses are L-acofriose (6-deoxy-3-0-methyl-L-mannose) (18), l-acovenose (6-deoxy-3-6>-methyl-L-talose) (19), o-allometh-ylose (6-deoxy-D-allose) (20), L-altromethylose (6-deoxy-L-altrose) (21), D-antiarose (6-deoxy-o-gulose) (22), D-boivi-nose (2,6-dideoxy-D-xy/o-hexose) (17), D-cymarose (2,6-di-... 

Me 6-Deoxy-3-0-methyl-L-mannose, 9CI. 3-O-Methyl-L-rhamnose. Acofriose... 

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