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Kramers’ theory energy diffusion regime

This ensures the correct connection between the one-dimensional Kramers model in the regime of large friction and multidimensional unimolecular rate theory in that of low friction, where Kramers model is known to be incorrect as it is restricted to the energy diffusion limit. For low damping, equation (A3.6.29) reduces to the Lindemann-Hinshelwood expression, while in the case of very large damping, it attains the Smoluchowski limit... [Pg.849]

Berezhkovskii A M and Zitserman V Yu 1993 Multi-dimensional Kramers theory of the reaction rate with highly anisotropio friotion. Energy diffusion for the fast coordinate versus overdamped regime for the slow coordinate Chem. Phys. Lett. 212 413-19... [Pg.866]

See other pages where Kramers’ theory energy diffusion regime is mentioned: [Pg.891]    [Pg.16]    [Pg.21]    [Pg.34]    [Pg.16]    [Pg.21]    [Pg.34]    [Pg.137]    [Pg.889]    [Pg.891]    [Pg.51]    [Pg.52]    [Pg.16]    [Pg.34]   
See also in sourсe #XX -- [ Pg.451 ]



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