Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Kramers Moyal equation

Taking the Taylor expansion in e, one obtains the backward and forward Kramers-Moyal equations ... [Pg.102]

Finally we note that the Master Equation, Eq. (15), may be formally expanded in the Kramers-Moyal series8... [Pg.69]

This is called the Kramers-Moyal expansion. ) Formally (2.6) is identical with the master equation itself and is therefore not easier to deal with, but it suggests that one may break off after a suitable number of terms. The Fokker-Planck approximation assumes that all terms after v = 2 are negligible. Kolmogorov s proof is based on the assumption that av = 0 for v>2. This, however, is never true in physical systems In the next chapter we shall therefore expand the M-equation systematically in powers of a small parameter and find that the successive orders do not simply correspond to the successive terms in the Kramers-Moyal expansion. [Pg.199]

Exercise. Write the Kramers-Moyal expansion for one-step processes using (5.2). Exercise. Construct the Fokker-Planck approximation for the M-equation (VI.9.12) and use it to find [Pg.209]

First it is clear that for each sample function L equation (4.3) uniquely determines y(t) when y(0) is given. Since the values of L at different times are stochastically independent, it follows that y is Markovian. Hence it obeys an M-equation, which may be written in the Kramers-Moyal form (VIII.2.6). We compute the successive coefficients (VIII.2.4). [Pg.229]

Incidentally, suppose one replaces the M-equation (3.4) by the naive Fokker-Planck approximation (VIII.5.3), obtained by breaking off the Kramers-Moyal expansion after the second term rather than by the systematic expansion of chapter X. This cannot be correct for small n and cannot therefore reproduce the evolution starting from small initial m. It is therefore not paradoxical that the absorbing site n = 0 does not translate into an absorbing boundary condition of the Fokker-Planck equation - as remarked in an Exercise of XII.5. [Pg.341]

It is of importance to point out that if the right-hand side is truncated after two terms (diffusion approximation), the last relation leads to an expression similar to the familiar Fokker-Planck equation (4.116). The approximation of a master equation of a birth-death process by a diffusion equation can lead to false results. Van Kampen has critically examined the Kramers-Moyal expansion and proposed a procedure based on the concept of system size expansion.135 It can be stated that any diffusion equation can be approximated by a one-step process, but the converse is not true. [Pg.102]

Another most important question in anomalous dielectric relaxation is the physical interpretation of the parameters a and v in the various relaxation formulas and what are the physical conditions that give rise to these parameters. Here we shall give a reasonably convincing derivation of the fractional Smoluckowski equation from the discrete orientation model of dielectric relaxation. In the continuum limit of the orientation sites, such an approach provides a justification for the fractional diffusion equation used in the explanation of the Cole-Cole equation. Moreover, the fundamental solution of that equation for the free rotator will, by appealing to self-similarity, provide some justification for the neglect of spatial derivatives of higher order than the second in the Kramers-Moyal expansion. In order to accomplish this, it is first necessary to explain the concept of the continuous-time random walk (CTRW). [Pg.294]

D.2. The Kramers-Moyal Expansion Coefficients for Nonlinear Langevin Equations... [Pg.447]

Stratonovich [12] finds the Kramers-Moyal [31] coefficients for an equation of this form to be... [Pg.448]

D.3. Evaluation of the Kramers-Moyal Coefficients for the Gilbert-Langevin Equation... [Pg.448]

We next evaluate the Kramers-Moyal coefficients for the Gilbert-Langevin equation using the Stratonovich method. Here we define G, =... [Pg.448]

D.4. Formulation of the Fokker-Planck Equation from the Kramers-Moyal Expansion Coefficients... [Pg.451]

For the absolute density function g the Kramers-Moyal-Stratonovich equation (Kramers, 1940 Moyal, 1949 Stratonovich, 1963) can be derived ... [Pg.98]

Our starting point is the Kramers-Moyal-Stratonovich equation (5.13). Neglecting the higher-than-first-order conditional moments the drift equation is obtained ... [Pg.115]

The Fokker-Planck equation, also referred to as the Smoluchowski equation or the generalized diffusion equation, neglects the moments of order larger than 2. Higher order terms appears in the Kramers-Moyal expansion [78]. [Pg.200]

Kramers-Moyal Expansion and the Fokker-Planck equation... [Pg.265]

Starting from the master equation (3.14) the stochastic equation and subsequently the Fokker-Planck equation - using the Kramers Moyal expansion - can be derived in a general and straight forward manner. [Pg.62]

The expansion in Eq. 13.65 is known as the Kramers-Moyal expansion. Assuming that D (x) = 0 for > 2, yields the Fokker-Planck equation... [Pg.229]

The linear treatment of the noise in equation (11.7) has cast some doubt on the validity of the fl expansion. Therefore, a different class of Fokker-Planck equations have been proposed that keep the nonlinearities of the master equation. Kramers and Moyal have treated the shifts nio 1, 1... [Pg.302]


See other pages where Kramers Moyal equation is mentioned: [Pg.57]    [Pg.58]    [Pg.57]    [Pg.58]    [Pg.78]    [Pg.67]    [Pg.32]    [Pg.293]    [Pg.417]    [Pg.420]    [Pg.411]    [Pg.301]    [Pg.111]    [Pg.3140]   
See also in sourсe #XX -- [ Pg.101 ]




SEARCH



Kramer

Kramer equation

Kramers

Kramers’ equation

© 2024 chempedia.info