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Kosower s radical

Kosower s radical (66) reacts with alkyl halides by a mechanism which transfers a halogen atom to the pyridinyl radical in the rate determining step (Py is 66) ... [Pg.252]

A third method would be to to use a push-pull substituent effect [411 or the capto-dative or merostabilization method. An example of this is Kosower s radical [42] (l-ethyl-4-carbomethoxypyridinyl). This method has not yet been used to form organic metals. [Pg.5]

N. S. Kosower and E. M. Kosower, The glutathione-glutathione disulfide system, Free Radicals Biol. 2, 55-84 (1976). [Pg.56]

Fig. 14. Electronic spectra of radicals 82 and 83 and results of the semiempirical calculations. (Taken from Hilnig, S. el al., Ref. t9t>). Assignment of strong absorption at 40 AK to 83 is uncertain (Kosower, E. M., Cotter, J. L., Ref. roo) g,nd private communication)... Fig. 14. Electronic spectra of radicals 82 and 83 and results of the semiempirical calculations. (Taken from Hilnig, S. el al., Ref. t9t>). Assignment of strong absorption at 40 AK to 83 is uncertain (Kosower, E. M., Cotter, J. L., Ref. roo) g,nd private communication)...
See other pages where Kosower s radical is mentioned: [Pg.147]    [Pg.249]    [Pg.147]    [Pg.5]    [Pg.147]    [Pg.249]    [Pg.147]    [Pg.5]    [Pg.305]    [Pg.117]   
See also in sourсe #XX -- [ Pg.4 ]



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