Kinetic studies of keto-enol and other

Kinetic studies of keto-enol and other tautomeric equilibria by flash photolysis... 

Kinetics and spectroscopy of substituted phenylnitrenes, 36, 255 Kinetics, of organic reactions in water and aqueous mixtures, 14, 203 Kinetics, reaction, polarography and, 5, 1 Kinetic studies of keto—enol and other tautomeric equilibria by flash photolysis, 44, 325... 

Wirz, J. (2010) Kinetic studies of Keto-Enol and other tautomeric equilibria by flash photolysis. Adv. Phys. Org. Chem., 44, 325-356. 

It has been noted that a positive activation volume (8.0 cm moP ) for the incorporation of Co " into N-methyltetraphenylporphyrin in DMF is consistent with an Id mechanism. The kinetics of the dissociation of the five-coordinate cobalt(II) complex of tris(2-dimethylaminoethyl)amine in solutions of chloroacetic acid in DMF and other solvents have been repor-ted, but no firm conclusions are drawn concerning the mechanism. The formation of the pentane-2,4-dione complex of Co(II) in aqueous solution has been studied/ and the values of kf for the reaction of the enol and keto tautomers (respectively, 136 and 0.84dm mor s 25 C, / = 0.5 mol dm ) found to be considerably lower than those predicted on the basis of the solvent exchange rate for this metal. 

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