Kinetic modeling lumped acids

Kinetic Model 2 (KM 2) lumped acids and CO2 production The kinetic model 1 considers only the oxidation of the major aromatic intermediates. As shown in the previous section, when most of the major intermediates have been depleted, there is still a substantial concentration of other remaining organic intermediates, as the TOC profile indicates. Therefore, it is of particular interest to calculate and predict the total mineralization times. Also, with TOC measurements, it is possible to approximate the amount of CO2 produced in the course of the reaction. In this new series-parallel model, the formation and disappearance of carboxylic acids as well as the production of CO2 has been incorporated. 

Cao, G., Viola, A., Baratti, R., Morbidelli, M., Sanseverino, L., and Cruccu, M., Lumped kinetic model for propene-butene mixtures oligomerization on a supported phosphoric acid catalyst. Adv. Catal. 41,301 (1988). 

Langmuir-Hinshelwood kinetics adsorption inhibition, 62 consistency of, 66 rate-controlling step for, 60 two-step model for, 67 Langmuir-Hinshelwood mechanism, 60 Lewis acid, 6 Lewis number definition of, 107 stability as affected by, 266 Local activity factor, 465 Lumping, 81... 

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