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Kinetic model of pyrolysis

KINETIC MODELLING OF PYROLYSIS PROCESSES IN GAS AND CONDENSED PHASE... [Pg.51]

Nowadays, improved computing facilities and, more importantly, the availability of the Chemkin package (Kee and Rupley, 1990) and similar kinetic compilers and processors have made these complex kinetic schemes more user-friendly and allows the study of process alternatives as well as the design and optimization of pyrolysis coils and furnaces. In spite of their rigorous, theoretical approach, these kinetic models of pyrolysis have always been designed and used for practical applications, such as process simulation, feedstock evaluations, process alternative analysis, reactor design and optimization, process control and so on. Despite criticisms raised recently by Miller et al. (2005), these detailed chemical kinetic models constitute an excellent tool for the analysis and understanding of the chemistry of such systems. [Pg.53]


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