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Key Strategies for C-H Bond Cleavage Reactions

Key Strategies for C-H Bond Cleavage Reactions 14.2.2.1 Coordinative Unsaturation [Pg.352]

In the reaction of cis-RuH2(PPh3)4 with alkyl methacrylate, regioselective sp C-H bond cleavage takes place to give a ruthenacycle complex (Eq. 14.1) [35]. [Pg.353]

By virtue of the intramolecular anchoring bonding, sp C-H bond activation may become possible. Treatment of Ru(l,5-COD)(l,3,5-COT) with (ortho)-substituted phenols resulted in the successive O-H and sp C-H bond-cleavage reactions, giving [Pg.353]



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C cleavage

C-0 bond cleavage

C-H bond cleavage reaction

C-H cleavage

Cleavage reaction

Cleavage strategies

C—H bond cleavage

For cleavage

Key reaction strategy

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