Ketones singly occupied molecular orbital

Mastracchio A, Warkentin AA, Walji AM, MacMillan DWC (2010) Direct and Enantioselective a-Allylation of Ketones via Singly Occupied Molecular Orbital (SOMO)... [Pg.155]

Singly occupied molecular orbital (SOMO) catalysis has been successfully employed in an enantioselective organocatalytic a-allylation of cyclic ketones, using commercially available allylsilanes. (g)... [Pg.27]

The first enantioselective organocatalytic a-allylation of cyclic ketones has been accomphshed via singly occupied molecular orbital catalysis. " Geometrically constrained radical cations (i.e., 196), forged from the one-electron oxidation of transiently generated enamines, readily undergo aUylic alkylation with a variety of commercially available allyl silanes to give 197 (Scheme 25.91). [Pg.760]