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Rearrangement aryl ketones

Chiral boronic esters react with organolithium reagents to form diorganylalkoxyboranes (borinic esters). Subsequent reaction with the anion of dichloromethyl methyl ether then yields chiral ketones by rearrangement of both of the groups on boron (Scheme 42). No racemization is observed in this sequence and alkyl-, aryl- or alkynyl-lithium reagents can be used. [Pg.797]

Scheme 17 Formation of ketones 56 and 58 via a catal5 ic 1,2-aryl rearrangement... Scheme 17 Formation of ketones 56 and 58 via a catal5 ic 1,2-aryl rearrangement...
The preference for O acylation of phenols arises because these reactions are kmetically controlled O acylation is faster than C acylation The C acyl isomers are more stable how ever and it is known that aluminum chloride is a very effective catalyst for the conversion of aryl esters to aryl ketones This isomerization is called the Fries rearrangement... [Pg.1006]

CH2CO via rearrangement from a methyl ketone or an aromatic acetate or an aryl-NHCOCHj group... [Pg.816]

Substituents R, R at the starting oxime 1 can be H, alkyl, or aryl. The reaction conditions for the Beckmann rearrangement often are quite drastic (e.g. concentrated sulfuric acid at 120 °C), which generally limits the scope to less sensitive substrates. The required oxime can be easily prepared from the respective aldehyde or ketone and hydroxylamine. [Pg.32]

A ketoxime tosylate 1 can be converted into an a-amino ketone 2 via the Neber rearrangement by treatment with a base—e.g. using an ethoxide or pyridine. Substituent R is usually aryl, but may as well be alkyl or H substituent R can be alkyl or aryl, but not H. [Pg.209]

Fukumoto epoxide rearrangement is worthy of note, in that a stereoselective rearrangement occurs spontaneously during the SAE of a 2-aryl-2-cyclopropylide-neethanol (194), prepared from ketone 193, to give the geminally substituted cydo-... [Pg.305]

Symmetrical ketones can be prepared in good yields by the reaction of organo-mercuric halides with dicobalt octacarbonyl in THF, or with nickel carbonyl in DMF or certain other solvents. The R group may be aryl or alkyl. However, when R is alkyl, rearrangements may intervene in the C02(CO)g reaction, though the Ni(CO)4 reaction seems to be free from such rearrangements. Divinylic ketones... [Pg.800]


See other pages where Rearrangement aryl ketones is mentioned: [Pg.1015]    [Pg.1015]    [Pg.1015]    [Pg.52]    [Pg.164]    [Pg.121]    [Pg.100]    [Pg.432]    [Pg.247]    [Pg.154]    [Pg.110]    [Pg.116]    [Pg.78]    [Pg.774]    [Pg.302]    [Pg.229]    [Pg.252]    [Pg.580]    [Pg.82]    [Pg.702]    [Pg.1018]    [Pg.1397]    [Pg.1406]    [Pg.1410]    [Pg.1411]    [Pg.1415]    [Pg.1417]    [Pg.1567]    [Pg.255]   
See also in sourсe #XX -- [ Pg.490 ]

See also in sourсe #XX -- [ Pg.490 ]

See also in sourсe #XX -- [ Pg.98 , Pg.490 ]




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Aryl ketones

Aryl rearrangements

Ketones arylation

Ketones rearrangement

Ketones, 2-haloalkyl aryl rearrangement

Ketones, aryl oxidative rearrangement

Ketones, aryl via rearrangement of arylalkenes

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